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Effect of N-alkylbetaines on the corrosion of iron in 1 M HCI solution

Identifieur interne : 000240 ( Maroc/Analysis ); précédent : 000239; suivant : 000241

Effect of N-alkylbetaines on the corrosion of iron in 1 M HCI solution

Auteurs : N. Hajjaji [Maroc] ; I. Rico ; A. Srhiri [Maroc] ; A. Lattes ; M. Soufiaoui ; A. Ben Bachir [Maroc]

Source :

RBID : Pascal:93-0554319

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English descriptors

Abstract

Using potentiodynamic and transient electrochemical methods and weight loss shows that N-alkyltaines are good inhibitors of iron corrosion in HCl at concentrations around the critical micelle concentration (CMC). High corrosion inhibition is observed when medium pH value is lower than organic compound pKa. When the concentration is close to the CMC, the organic compounds operate on the anodic and cathodic process and a bimolecular layer is formed. The inhibiting etfect is reduced with an increase of medium pH value. This is explained by the complexing of NaBr with the zwitterionic form of organic compounds


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Pascal:93-0554319

Le document en format XML

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<term>Acid medium</term>
<term>Adsorption</term>
<term>Betaine</term>
<term>Cobalt Carbon Alloys</term>
<term>Concentration effect</term>
<term>Corrosion inhibitor</term>
<term>Corrosion potential</term>
<term>Corrosion protection</term>
<term>Hydrogen Chlorides</term>
<term>Hydrogen chlorides</term>
<term>Iron</term>
<term>Organic compounds</term>
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<term>Inhibiteur corrosion</term>
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<term>Composé organique</term>
<term>Milieu acide</term>
<term>Bétaïne</term>
<term>Cobalt Carbone Alliage</term>
<term>Potentiel corrosion</term>
<term>Effet concentration</term>
<term>Adsorption</term>
<term>Protection corrosion</term>
<term>Hydrogène Chlorure</term>
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<div type="abstract" xml:lang="en">Using potentiodynamic and transient electrochemical methods and weight loss shows that N-alkyltaines are good inhibitors of iron corrosion in HCl at concentrations around the critical micelle concentration (CMC). High corrosion inhibition is observed when medium pH value is lower than organic compound pKa. When the concentration is close to the CMC, the organic compounds operate on the anodic and cathodic process and a bimolecular layer is formed. The inhibiting etfect is reduced with an increase of medium pH value. This is explained by the complexing of NaBr with the zwitterionic form of organic compounds</div>
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